Boyle's Law (Concept and Example)
If you trap a sample of air and measure its volume at different pressures (constant temperature), then you can determine a relation between volume and pressure. If you do this experiment, you will find that as the pressure of a gas sample increases, its volume decreases. In other words, the volume of a gas sample at constant temperature is inversely proportional to its pressure. The product of the pressure multiplied by the volume is a constant: PV = k or V = k/P or P = k/V where P is pressure, V is volume, k is a constant, and the temperature and quantity of gas are held constant. This relationship is called Boyle's Law, after Robert Boyle, who discovered it in 1660. Worked Example Problem The sections on the General Properties of Gases and Ideal Gas Law Problems may also be helpful when attempting to work Boyle's Law problems. Problem A sample of helium gas at 25°C is compressed from 200 cm3 to 0.240 cm3. Its pressure is now 3.00 cm Hg. What was the original pressure of the...