Sunday, January 19, 2014

Calcium Facts

Chemical & Physical Properties of Calcium

 Calcium

Calcium Basic Facts:
Symbol: Ca
Atomic Number: 20
Atomic Weight: 40.078
Classification: Alkaline Earth
CAS Number: 7440-701-2
Calcium Periodic Table Location
Group: 2
Period: 4
Block: s
Calcium Electron Configuration
Short Form: [Ar]4s2
Long Form: 1s22s22p63s23p64s2


 

Shell Structure: 2 8 8 2
Calcium Discovery
Discovery Date: 1808
Discoverer: Sir Humphrey Davy [England]
Name: Calcium derives its name from the Latin 'calcis' which was the word for lime (calcium oxide, CaO) and limestone (calcium carbonate, CaCO3)
History: The Romans prepared lime in the first century, but the metal was not discovered until 1808. Swedish chemist Berzelius and Swedish court physician Pontin created an amalgam of calcium and mercury by electrolyzing lime and mercury oxide. Davy managed to isolate pure calcium metal from their amalgam.


Calcium Physical Data
State at room temperature (300 K): Solid
Appearance: fairly hard, silvery white metal
Density: 1.55 g/cc
Specific Gravity: 1.55 (20 °C)
Melting Point: 1115 K
Boiling Point: 1757 K
Critical Point: 2880 K
Heat of Fusion: 8.54 kJ/mol
Heat of Vaporization: 154.7 kJ/mol
Molar Heat Capacity: 25.929 J/mol·K
Specific Heat: 0.647 J/g·K (at 20 °C)
Calcium Atomic Data
Oxidation States: +2 (most common), +1
Electronegativity: 1.00
Electron Affinity: 2.368 kJ/mol
Atomic Radius: 197 pm
Atomic Volume: 29.9 cc/mol
Ionic Radius: 99 (+2e)
Covalent Radius: 174 pm
Van der Waals Radius: 231 pm
First Ionization Energy: 589.830 kJ/mol
Second Ionization Energy: 1145.446 kJ/mol
Third Ionization Energy: 4912.364 kJ/mol
Calcium Nuclear Data
Number of Naturally Occurring Isotopes: 6
Isotopes and % Abundance: 40Ca (96.941), 42Ca (0.647), 43Ca (0.135), 44Ca (2.086), 46Ca (0.004) and 48Ca (0.187)
Calcium Crystal Data
Lattice Structure: Face-Centered Cubic
Lattice Constant: 5.580 Å
Debye Temperature: 230.00 K

Calcium Uses:Calcium is essential for human nutrition. Animals skeletons get their rigidity primarily from calcium phosphate. The eggs of birds and shells of mollusks are comprised of calcium carbonate. Calcium is also necessary for plant growth. Calcium is used as a reducing agent when preparing metals from their halogen and oxygen compounds; as a reagent in purification of inert gases; to fix atmospheric nitrogen; as a scavenger and decarbonizer in metallurgy; and for making alloys. Calcium compounds are used in making lime, bricks, cement, glass, paint, paper, sugar, glazes, as well as for many other uses.
Miscellaneous Calcium Facts
  • Calcium is the 5th most abundant element in the Earth's crust, making up 3.22% of the earth, air, and oceans.
  • Calcium is not found free in nature, but calcium compounds are common. Some of the most common compounds found on Earth are limestone (calcium carbonate - CaCO3), gypsum (calcium sulfate - CaSO4·2H2O), fluorite (calcium fluoride - CaF2) and apatite (calcium fluorophosphate - CaFO3P or calcium chlorophosphate - CaClO3P)
  • The top three countries that produce calcium are China, United States and India.
  • Calcium is the main component of teeth and bones.
  • Calcium is the fifth most abundant element in the human body. Approximately one third of the mass of the human body is calcium after all water is removed.
  • Calcium burns with a dark red color in a flame test.
  • Calcium is used in fireworks to deepen the color. Calcium salts are used to produce orange in fireworks.
References:CRC Handbook of Chemistry & Physics (89th Ed.), National Institute of Standards and Technology, History of the Origin of the Chemical Elements and Their Discoverers, Norman E. Holden 2001.

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