Electrolysis of dilute sodium chloride solution
Electrolysis of concentrated sodium chloride solution
At
anode :
Anions : OH- and Cl-
OH- ions are selectively discharge according to the position of ions in the Electrochemical Series, ES.
Gas bubbles are formed which lighted up a glowing wooden splinter. This gas is oxygen.
4OH- ---> 2 H2O + O2 + 4e
At
anode :
Anions : OH- and Cl-
Cl- ions are discharged instead of OH- because of their higher concentration in the electrolyte.
A greenish-yellow gas with a pungent and choking smell is released. The gas turns the blue litmus paper red and then white.
2Cl- ---> Cl2 + 2e
At cathode:
Cations : H+ dan Na+
H+ ions are selectively discharge according to the position of ions in the ES.
Gas bubbles are formed. When a lighted wooden splinter is placed near the mouth of the test tube, a ‘pop’ sound is produced. Hydrogen gas is produced
2H+ + 2e ---> H2
At cathode:
Cations : H+ dan K+
H+ ions are selectively discharge according to the position of ions in the ES.
Gas bubbles are formed. When a lighted wooden splinter is placed near the mouth of the test tube, a ‘pop’ sound is produced. Hydrogen gas is produced
2H+ + 2e ---> H2
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